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Benzyle benzoate overview.
Name (Merck Index): Benzyl benzoate
Used for control of: As an insect repellent and pediculicide and scabicide.
Trade names:
  • Ascabin
  • Ascabiol
  • Benylate
  • Benzylets
  • Colebenz
  • Novoscabin
  • Peruscabin
  • Scabagen
  • Scabanca
  • Scabide
  • Scabiozon
  • Unichem BZBM
  • Vanzoate
  • Venzonate
Available for distribution as: No longer in agricultural use.
Manufacturers: None found for agricultural use.
Risk to humans and mammals: Extremely low toxicity to humans and other mammals- used as a flavorant. Is irritating to eyes and mucous membranes and may affect the skin in some individuals.
Risk and Hazard Warnings
  • Harmful if swallowed
  • Keep out of reach of children
  • Avoid contact with eyes
Warning Symbols
First Aid Rinse affected areas copiously with water. If irritation develops, consult a physician.
Risk to other animals: Very low.
Risk to plants: Very low.
Other comments: Benzyl benzoate is a component of cinnamon oil and Peru and Tolu balsams. It was first selected as an insect repellent by the US Army in 1945. It replaced the less successful dimethyl phthalate in part because it could survive laundering after uniforms had been impregnated with it. It is probably no longer available (or certified in the United States for use) as an insect repellent. However, it has a number of uses in the food and chemical industries and may be available in quantity if needed.
Chemical Structure:
Chemical Abstracts name: Benzoic acid phenylmethyl ester
Registry number
(CAS#):
120-51-4
IUPAC name: Benzyl benzoate
RTECS number: DG4200000
Chemical properties: Liquid at room temperatures, slightly volatile and soluble or miscible with organic solvents.
Other trivial names:
  • Benzoic acid benzyl ester
  • Benzyl benzenecarboxylate
  • Benzyl phenylformate
  • Phenylmethyl benzoate
Pesticides can only be regarded as safe if used in accordance with the manufacturer's instructions.
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