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Nerve Agent Precursor: Phosphorus Trichloride

CA Index Name Phosphorus trichloride
CAS Registry Number 7719-12-2 RTECS Number TH3675000
EINECS Number
233-046-7 UN Transport Code
1810
ICSC Number
0696
CWC Schedule 3B

 

Warning symbols
Toxic

 

Synonyms: Phosphorous chloride
Trichlorophosphine

CHEMICAL AND PHYSICAL PROPERTIES

Structural Formula

Liquid at STP
Molecular
Formula
PCl3 Molecular
Weight
137.35
Boiling
Point
76.1° Melting
Point
-93.6°
Vapor
Density
4.8 Liquid
Density
1.6
Vapor pressure
13.3 kPa at 21°C
Not flammable

 

NFPA Hazard Ratings
FIRE
0
HEALTH
4
REACTIVITY
2

SPECIAL
reactive with water

Also refer to 2000 Emergency Response Guidebook (ERG2000) Guide 137.

 


Initial Isolation and Protective Action Distances

 

SMALL RELEASE

(small package/leaking container)

First
ISOLATE
in all directions
Then
PROTECT
persons downwind during
DAY NIGHT
Spill on
Land
30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi)
Spill on
Water
30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi)
 

LARGE RELEASE

(large package/multiple small packages)

First
ISOLATE
in all directions
Then
PROTECT
persons downwind during
DAY NIGHT
Spill on
Land
125 m (400 ft) 1.1 km (0.7 mi) 2.7 km (1.7 mi)
Spill on
Water
95 m (300 ft) 1.0 km (0.6 mi) 2.6 km (1.6 mi)

Health Hazards

Eye, skin and inhalational irritant, may be fatal if swallowed. Should be handled with care using protective clothing

It is actually difficult to determine the true toxicity of phosphorus trichloride as most of the toxic effects arise from degradation and reaction products.

Reactive with water and can react explosively. Does not burn but will decompose in a fire to give off toxic fumes.

INDUSTRIAL/COMMERCIAL USES

Phosphorus trichloride is a remarkably versatile reagent and can be used to introduce chlorine or phosphorus into a wide range of inorganic and organic precursors. Annual production in the United States is in excess of 300,000 short tons with US consumption in excess of 350,000 short tons. Approximately 70% of this is used in the manufacture of organophosphorus pesticides including glyphosate, the active component of Roundup. A further 12% is used in the manufacture of phosphorus oxychloride. Another 12% is used in surfactants and water processing chemicals and the remainder in plastic processing and in oil and plate additives.

The industrial manufacture of phosphorus trichloride helps to demonstrate the limits of control of weapons precursors. It is manufactured by the controlled reaction of chlorine and elemental phosphorus. The reaction is highly energetic and presents an engineering challenge, although it is not insuperable. Chlorine and elemental phosphorus are produced in large quantities: The US produced over 11 million tons of chlorine in 2002 and slightly less than 11 million tons of phosphoric acid in the same period.. Short of controlling all of the traffic in the two elements, and the chemical plant used to make phosphorus trichloride, there are limits on how well trade in this compound can be policed.

 

COMMENTS

Aum Shinrikyo claimed that the quantities of phosphorus trichloride found at the Satyam 7 plant was for use in the manufacture of plastic computer cases.

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